# Supplementary Material (ESI) for Organic & Biomolecular Chemistry
# This journal is © The Royal Society of Chemistry 2003

data_global

_journal_coden_Cambridge         177

loop_
_publ_author_name
'Timothy Donohoe'
'Andrew Bell'
'Madeleine Helliwell'
'Lee Mitchell'
'Nicholas J. Newcombe'
'Michael J. Waring'

_publ_contact_author_name        'Dr Timothy Donohoe'
_publ_contact_author_address     
;
Chemistry
University of Oxford
Dyson Perrins Laboratory
South Parks Road
Oxford
OXON
OX1 3QY
UNITED KINGDOM
;

_publ_contact_author_email       TIMOTHY.DONOHOE@CHEM.OX.AC.UK

_publ_requested_journal          'Organic & Biomolecular Chemistry'

_publ_section_title              
;
Scope of the Directed Dihydroxylation: Application
to Cyclic Homoallylic Alcohols and Trihaloacetamide
;

data_S667
_database_code_CSD               207038
#------------------------------------------------------------------------------
_audit_creation_date             1998-06-16
_audit_creation_method           'by teXsan v1.7'
_audit_update_record             
;
?
;

_publ_section_references         
;
ENTER OTHER REFERENCES

Molecular Structure Corporation. (1995). teXsan. 
Single Crystal Structure Analysis Software. Version 1.7.
MSC, 3200 Research Forest Drive, The Woodlands, TX 77381, USA.

North, A.C.T., Phillips, D. C. & Mathews, F. S. (1968).
Acta Cryst. A24, 351-359.

Zachariasen, W. H. (1967). Acta Cryst. 23, 558-564.
;

#------------------------------------------------------------------------------
loop_
_publ_manuscript_incl_extra_item
'_geom_extra_table_head_3'
'_geom_bond_atom_site_label_D'
'_geom_bond_atom_site_label_H'
'_geom_contact_atom_site_label_A'
'_geom_bond_distance_DH'
'_geom_contact_distance_HA'
'_geom_contact_distance_DA'
'_geom_angle_DHA'
'_geom_contact_site_symmetry_A'
#
#
#------------------------------------------------------------------------------
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan (MSC, 1995)'
_computing_structure_solution    ?
_computing_structure_refinement  'teXsan (MSC, 1995)'
_computing_publication_material  'teXsan (MSC, 1995)'
#------------------------------------------------------------------------------
_cell_length_a                   11.595(6)
_cell_length_b                   12.862(5)
_cell_length_c                   11.561(6)
_cell_angle_alpha                101.31(4)
_cell_angle_beta                 119.63(3)
_cell_angle_gamma                73.15(3)
_cell_volume                     1431(1)
_cell_formula_units_Z            2
_cell_measurement_temperature    296.2
_cell_measurement_reflns_used    0
_cell_measurement_theta_min      0.0
_cell_measurement_theta_max      0.0
#------------------------------------------------------------------------------
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  ?
loop_
_symmetry_equiv_pos_as_xyz
'   +x,   +y,   +z'
'   -x,   -y,   -z'
#------------------------------------------------------------------------------
_exptl_crystal_description       unknown
_exptl_crystal_colour            unknown
_exptl_crystal_size_max          0.00
_exptl_crystal_size_mid          0.00
_exptl_crystal_size_min          0.00
_exptl_crystal_density_diffrn    1.749
_exptl_crystal_density_meas      'not measured'
_chemical_formula_weight         753.98
_chemical_formula_analytical     ?
_chemical_formula_sum            'C19 H36 Cl5 N3 O5 Os '
_chemical_formula_moiety         ?
_chemical_formula_structural     ?
_chemical_compound_source        ?
_exptl_crystal_F_000             744.00
_exptl_absorpt_coefficient_mu    4.950
_exptl_absorpt_correction_type   
;
\y scans (North,Phillips & Matthews, 1968)
;
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.799
_exptl_special_details           
;
The scan width was (0.00+0.00tan\q)\% with an \w
scan speed of 0\% per minute 
.
Stationary background counts were recorded at each end of the
scan, and the scan time:background time ratio was 2:1.
;
#------------------------------------------------------------------------------
_diffrn_special_details          
;
?
;
_diffrn_ambient_temperature      296.2
_diffrn_radiation_wavelength     0.7107
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_detector       'scintillation counter'
_diffrn_measurement_device       'Rigaku AFC6S'
_diffrn_measurement_method       ?

_diffrn_standards_number         3
_diffrn_standards_interval_count 0
_diffrn_standards_decay_%        -0.43
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
-4 0 2
-3 2 2
-5 -2 3
_diffrn_reflns_number            5326
_reflns_number_total             5053
_reflns_number_observed          4202
_reflns_observed_criterion       >2.00\s(I)
_diffrn_reflns_av_R_equivalents  0.02308
_diffrn_reflns_av_sigmaI/netI    0.060
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         1.66
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_orient_matrix_UB_11      -0.03506
_diffrn_orient_matrix_UB_12      -0.00776
_diffrn_orient_matrix_UB_13      0.06066
_diffrn_orient_matrix_UB_21      -0.03520
_diffrn_orient_matrix_UB_22      0.08066
_diffrn_orient_matrix_UB_23      0.00460
_diffrn_orient_matrix_UB_31      -0.08892
_diffrn_orient_matrix_UB_32      -0.00777
_diffrn_orient_matrix_UB_33      -0.07900
#------------------------------------------------------------------------------
loop_
_atom_type_symbol
_atom_type_oxidation_number
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C 0 38 0.003 0.002
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
H 0 72 0.000 0.000
;International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.2)
;
O 0 10 0.011 0.006
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
N 0 6 0.006 0.003
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
Cl 0 10 0.148 0.159
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
Os 0 2 -1.216 7.603
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
#------------------------------------------------------------------------------
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_occupancy
_atom_site_refinement_flags
_atom_site_thermal_displace_type
_atom_site_calc_flag
_atom_site_calc_attached_atom
Os(1) 0.15589(3) 0.15394(2) 0.32908(3) 0.02916(8) 1.000 . Uani d ?
Cl(1) -0.1624(2) 0.5677(2) 0.0466(2) 0.0508(6) 1.000 . Uani d ?
Cl(2) -0.0648(2) 0.7469(2) 0.0428(2) 0.0554(6) 1.000 . Uani d ?
Cl(3) -0.1415(2) 0.7466(2) 0.2459(2) 0.0622(7) 1.000 . Uani d ?
Cl(4) 0.4903(4) 0.0707(2) 0.8306(4) 0.126(1) 1.000 . Uani d ?
Cl(5) 0.5011(4) -0.1555(3) 0.8339(3) 0.115(1) 1.000 . Uani d ?
O(1) 0.1635(5) 0.1635(4) 0.4846(4) 0.040(1) 1.000 . Uani d ?
O(2) 0.1142(5) 0.1177(4) 0.1621(5) 0.043(2) 1.000 . Uani d ?
O(3) 0.3470(5) 0.1507(3) 0.3933(5) 0.037(1) 1.000 . Uani d ?
O(4) 0.1276(5) 0.3101(3) 0.3167(4) 0.035(1) 1.000 . Uani d ?
O(5) 0.1652(5) 0.6718(4) 0.3000(6) 0.059(2) 1.000 . Uani d ?
N(1) 0.1838(6) -0.0228(4) 0.3428(6) 0.038(2) 1.000 . Uani d ?
N(2) -0.0635(6) 0.1547(5) 0.2553(6) 0.040(2) 1.000 . Uani d ?
N(3) 0.1097(6) 0.5111(4) 0.2715(5) 0.035(2) 1.000 . Uani d ?
C(1) 0.2971(8) -0.0594(6) 0.4748(8) 0.057(3) 1.000 . Uani d ?
C(2) 0.2119(9) -0.0932(6) 0.2373(9) 0.059(3) 1.000 . Uani d ?
C(3) 0.0527(9) -0.0324(6) 0.3313(9) 0.054(3) 1.000 . Uani d ?
C(4) -0.0679(8) 0.0359(6) 0.2262(9) 0.053(3) 1.000 . Uani d ?
C(5) -0.1116(8) 0.2068(7) 0.3550(9) 0.063(3) 1.000 . Uani d ?
C(6) -0.1548(8) 0.2114(7) 0.1304(9) 0.063(3) 1.000 . Uani d ?
C(7) 0.3719(7) 0.2586(5) 0.4272(7) 0.032(2) 1.000 . Uani d ?
C(8) 0.2476(7) 0.3314(5) 0.3270(6) 0.030(2) 1.000 . Uani d ?
C(9) 0.2438(7) 0.4525(5) 0.3649(6) 0.033(2) 1.000 . Uani d ?
C(10) 0.2723(7) 0.4818(5) 0.5094(7) 0.034(2) 1.000 . Uani d ?
C(11) 0.4121(7) 0.4141(5) 0.6025(6) 0.031(2) 1.000 . Uani d ?
C(12) 0.4055(7) 0.2939(5) 0.5697(6) 0.034(2) 1.000 . Uani d ?
C(13) 0.0844(7) 0.6146(6) 0.2477(7) 0.037(2) 1.000 . Uani d ?
C(14) -0.0647(7) 0.6653(5) 0.1475(6) 0.035(2) 1.000 . Uani d ?
C(15) 0.4599(7) 0.4517(5) 0.7518(7) 0.036(2) 1.000 . Uani d ?
C(16) 0.4752(8) 0.5692(6) 0.7772(7) 0.051(2) 1.000 . Uani d ?
C(17) 0.3589(9) 0.4444(7) 0.7975(8) 0.064(3) 1.000 . Uani d ?
C(18) 0.5987(9) 0.3799(6) 0.8375(7) 0.059(3) 1.000 . Uani d ?
C(19) 0.5905(10) -0.0566(8) 0.866(1) 0.081(4) 1.000 . Uani d ?
H(1a) 0.3010 -0.1342 0.4810 0.068 1.000 . Uiso c ?
H(1b) 0.3812 -0.0558 0.4823 0.068 1.000 . Uiso c ?
H(1c) 0.2824 -0.0163 0.5438 0.068 1.000 . Uiso c ?
H(2a) 0.2183 -0.1681 0.2466 0.071 1.000 . Uiso c ?
H(2b) 0.1408 -0.0733 0.1520 0.071 1.000 . Uiso c ?
H(2c) 0.2961 -0.0883 0.2463 0.071 1.000 . Uiso c ?
H(3a) 0.0459 -0.1063 0.3085 0.065 1.000 . Uiso c ?
H(3b) 0.0535 -0.0104 0.4150 0.065 1.000 . Uiso c ?
H(3n) 0.034(5) 0.482(4) 0.237(5) 0.02(1) 1.000 . Uiso d ?
H(4a) -0.1490 0.0293 0.2229 0.064 1.000 . Uiso c ?
H(4b) -0.0699 0.0143 0.1427 0.064 1.000 . Uiso c ?
H(5c) -0.2038 0.2050 0.3223 0.075 1.000 . Uiso c ?
H(5a) -0.0561 0.1739 0.4362 0.075 1.000 . Uiso c ?
H(5b) -0.1074 0.2840 0.3714 0.075 1.000 . Uiso c ?
H(6c) -0.2472 0.2104 0.1007 0.076 1.000 . Uiso c ?
H(6a) -0.1504 0.2888 0.1478 0.076 1.000 . Uiso c ?
H(6b) -0.1291 0.1818 0.0642 0.076 1.000 . Uiso c ?
H(7) 0.4472 0.2604 0.4159 0.039 1.000 . Uiso c ?
H(8) 0.2456 0.3166 0.2427 0.035 1.000 . Uiso c ?
H(9) 0.3110 0.4712 0.3535 0.037 1.000 . Uiso c ?
H(10b) 0.2038 0.4662 0.5216 0.040 1.000 . Uiso c ?
H(10a) 0.2713 0.5574 0.5300 0.040 1.000 . Uiso c ?
H(11) 0.4768 0.4251 0.5802 0.036 1.000 . Uiso c ?
H(12a) 0.3373 0.2846 0.5866 0.040 1.000 . Uiso c ?
H(12b) 0.4912 0.2520 0.6260 0.040 1.000 . Uiso c ?
H(16b) 0.5403 0.5734 0.7519 0.059 1.000 . Uiso c ?
H(16c) 0.3903 0.6150 0.7258 0.059 1.000 . Uiso c ?
H(16a) 0.5060 0.5898 0.8690 0.059 1.000 . Uiso c ?
H(17b) 0.2723 0.4920 0.7468 0.075 1.000 . Uiso c ?
H(17c) 0.3483 0.3729 0.7836 0.075 1.000 . Uiso c ?
H(17a) 0.3910 0.4684 0.8890 0.075 1.000 . Uiso c ?
H(18b) 0.6623 0.3875 0.8125 0.071 1.000 . Uiso c ?
H(18c) 0.6263 0.4058 0.9286 0.071 1.000 . Uiso c ?
H(18a) 0.5912 0.3081 0.8249 0.071 1.000 . Uiso c ?
H(19b) 0.6549 -0.0567 0.9576 0.096 1.000 . Uiso c ?
H(19a) 0.6365 -0.0770 0.8133 0.096 1.000 . Uiso c ?

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Os(1) 0.0330(2) 0.0215(1) 0.0312(2) -0.0054(1) 0.0132(1) 0.0006(1)
Cl(1) 0.047(1) 0.051(1) 0.049(1) -0.0242(10) 0.0093(10) 0.0023(10)
Cl(2) 0.063(1) 0.056(1) 0.046(1) -0.022(1) 0.011(1) 0.021(1)
Cl(3) 0.065(1) 0.054(1) 0.085(2) -0.017(1) 0.049(1) -0.014(1)
Cl(4) 0.156(3) 0.078(2) 0.155(3) 0.002(2) 0.091(3) 0.005(2)
Cl(5) 0.159(3) 0.115(3) 0.122(3) -0.075(2) 0.086(2) -0.021(2)
O(1) 0.048(3) 0.035(3) 0.036(3) -0.005(2) 0.021(3) -0.001(2)
O(2) 0.057(3) 0.036(3) 0.039(3) -0.016(3) 0.020(3) 0.005(2)
O(3) 0.036(3) 0.021(2) 0.050(3) -0.006(2) 0.018(2) -0.003(2)
O(4) 0.041(3) 0.019(2) 0.042(3) -0.005(2) 0.015(2) 0.001(2)
O(5) 0.044(3) 0.040(3) 0.082(4) -0.020(3) 0.003(3) 0.025(3)
N(1) 0.051(4) 0.023(3) 0.039(4) -0.009(3) 0.019(3) 0.005(3)
N(2) 0.033(4) 0.035(4) 0.049(4) -0.005(3) 0.015(3) 0.007(3)
N(3) 0.043(4) 0.030(3) 0.032(3) -0.021(3) 0.007(3) 0.005(3)
C(1) 0.054(6) 0.041(5) 0.063(6) 0.007(4) 0.018(5) 0.021(4)
C(2) 0.088(7) 0.024(4) 0.082(6) -0.009(4) 0.055(6) -0.009(4)
C(3) 0.057(6) 0.032(5) 0.081(7) -0.015(4) 0.029(5) 0.012(4)
C(4) 0.039(5) 0.043(5) 0.083(7) -0.021(4) 0.025(5) -0.001(5)
C(5) 0.049(5) 0.069(6) 0.081(7) -0.002(5) 0.043(5) -0.006(5)
C(6) 0.039(5) 0.069(6) 0.068(6) -0.003(4) 0.010(5) 0.022(5)
C(7) 0.026(4) 0.028(4) 0.037(4) -0.001(3) 0.015(3) -0.002(3)
C(8) 0.037(4) 0.025(4) 0.031(4) -0.007(3) 0.019(3) 0.001(3)
C(9) 0.038(4) 0.028(4) 0.035(4) -0.013(3) 0.013(3) 0.005(3)
C(10) 0.037(4) 0.031(4) 0.035(4) -0.007(3) 0.019(3) -0.002(3)
C(11) 0.034(4) 0.029(4) 0.034(4) -0.007(3) 0.017(3) 0.002(3)
C(12) 0.027(4) 0.030(4) 0.033(4) -0.005(3) 0.007(3) -0.002(3)
C(13) 0.041(4) 0.037(4) 0.036(4) -0.013(4) 0.014(4) 0.009(3)
C(14) 0.041(4) 0.031(4) 0.034(4) -0.016(3) 0.016(4) -0.005(3)
C(15) 0.034(4) 0.036(4) 0.033(4) -0.006(3) 0.012(3) 0.000(3)
C(16) 0.049(5) 0.047(5) 0.044(5) -0.014(4) 0.012(4) -0.008(4)
C(17) 0.083(7) 0.087(7) 0.042(5) -0.047(6) 0.036(5) -0.021(5)
C(18) 0.061(6) 0.053(5) 0.035(5) -0.005(4) 0.006(4) -0.003(4)
C(19) 0.068(7) 0.082(7) 0.108(8) -0.014(6) 0.054(7) -0.009(6)
#------------------------------------------------------------------------------
_refine_special_details          
;
?
;
_refine_ls_structure_factor_coef F
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      'w = 1/[\s^2^(Fo) + 0.00003|Fo|^2^]'
_refine_ls_hydrogen_treatment    ?
_refine_ls_extinction_method     'Zachariasen (1967)'
_refine_ls_extinction_coef       0.00000041(3)
_refine_ls_extinction_expression 'equ(3) Acta Cryst.(1968) A24, p213.'
_refine_ls_abs_structure_details ?
_refine_ls_abs_structure_Flack   ?
_refine_ls_number_reflns         4202
_refine_ls_number_parameters     303
_refine_ls_number_restraints     0
_refine_ls_number_constraints    0
_refine_ls_R_factor_all          0.0660
_refine_ls_R_factor_obs          0.0354
_refine_ls_wR_factor_all         0.0369
_refine_ls_wR_factor_obs         0.0316
_refine_ls_goodness_of_fit_all   1.609
_refine_ls_goodness_of_fit_obs   1.521
_refine_ls_shift/esd_max         0.0000
_refine_ls_shift/esd_mean        0.0000
_refine_diff_density_min         -0.79
_refine_diff_density_max         0.82
#------------------------------------------------------------------------------
_geom_special_details            
;
?
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Os(1) O(1) 1.737(4) . . yes
Os(1) O(2) 1.741(5) . . yes
Os(1) O(3) 1.948(5) . . yes
Os(1) O(4) 1.961(4) . . yes
Os(1) N(1) 2.227(5) . . yes
Os(1) N(2) 2.246(6) . . yes
Cl(1) C(14) 1.779(6) . . yes
Cl(2) C(14) 1.750(7) . . yes
Cl(3) C(14) 1.782(7) . . yes
Cl(4) C(19) 1.699(10) . . yes
Cl(5) C(19) 1.741(10) . . yes
O(3) C(7) 1.438(7) . . yes
O(4) C(8) 1.438(8) . . yes
O(5) C(13) 1.204(7) . . yes
N(1) C(1) 1.489(9) . . yes
N(1) C(2) 1.485(9) . . yes
N(1) C(3) 1.500(10) . . yes
N(2) C(4) 1.510(9) . . yes
N(2) C(5) 1.485(10) . . yes
N(2) C(6) 1.480(9) . . yes
N(3) C(9) 1.460(8) . . yes
N(3) C(13) 1.331(8) . . yes
N(3) H(3n) 0.93(5) . . no
C(1) H(1a) 0.97 . . no
C(1) H(1b) 0.95 . . no
C(1) H(1c) 0.94 . . no
C(2) H(2a) 0.97 . . no
C(2) H(2b) 0.94 . . no
C(2) H(2c) 0.95 . . no
C(3) C(4) 1.49(1) . . yes
C(3) H(3a) 0.95 . . no
C(3) H(3b) 0.95 . . no
C(4) H(4a) 0.95 . . no
C(4) H(4b) 0.94 . . no
C(5) H(5c) 0.95 . . no
C(5) H(5a) 0.94 . . no
C(5) H(5b) 0.98 . . no
C(6) H(6c) 0.95 . . no
C(6) H(6a) 0.99 . . no
C(6) H(6b) 0.93 . . no
C(7) C(8) 1.514(9) . . yes
C(7) C(12) 1.498(9) . . yes
C(7) H(7) 0.95 . . no
C(8) C(9) 1.526(8) . . yes
C(8) H(8) 0.95 . . no
C(9) C(10) 1.523(9) . . yes
C(9) H(9) 0.95 . . no
C(10) C(11) 1.539(9) . . yes
C(10) H(10b) 0.95 . . no
C(10) H(10a) 0.95 . . no
C(11) C(12) 1.533(8) . . yes
C(11) C(15) 1.551(9) . . yes
C(11) H(11) 0.96 . . no
C(12) H(12a) 0.95 . . no
C(12) H(12b) 0.94 . . no
C(13) C(14) 1.555(9) . . yes
C(15) C(16) 1.527(9) . . yes
C(15) C(17) 1.53(1) . . yes
C(15) C(18) 1.532(10) . . yes
C(16) H(16b) 0.95 . . no
C(16) H(16c) 0.94 . . no
C(16) H(16a) 0.95 . . no
C(17) H(17b) 0.96 . . no
C(17) H(17c) 0.94 . . no
C(17) H(17a) 0.95 . . no
C(18) H(18b) 0.95 . . no
C(18) H(18c) 0.96 . . no
C(18) H(18a) 0.93 . . no
C(19) H(19b) 0.95 . . no
C(19) H(19a) 0.95 . . no
#------------------------------------------------------------------------------
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O(1) Os(1) O(2) 161.9(2) . . . yes
O(1) Os(1) O(3) 96.8(2) . . . yes
O(1) Os(1) O(4) 96.9(2) . . . yes
O(1) Os(1) N(1) 82.7(2) . . . yes
O(1) Os(1) N(2) 83.1(2) . . . yes
O(2) Os(1) O(3) 97.4(2) . . . yes
O(2) Os(1) O(4) 95.7(2) . . . yes
O(2) Os(1) N(1) 84.5(2) . . . yes
O(2) Os(1) N(2) 82.5(2) . . . yes
O(3) Os(1) O(4) 84.6(2) . . . yes
O(3) Os(1) N(1) 96.6(2) . . . yes
O(3) Os(1) N(2) 179.1(2) . . . yes
O(4) Os(1) N(1) 178.8(2) . . . yes
O(4) Os(1) N(2) 96.4(2) . . . yes
N(1) Os(1) N(2) 82.5(2) . . . yes
Os(1) O(3) C(7) 111.5(4) . . . yes
Os(1) O(4) C(8) 109.5(4) . . . yes
Os(1) N(1) C(1) 110.8(4) . . . yes
Os(1) N(1) C(2) 113.6(4) . . . yes
Os(1) N(1) C(3) 104.6(4) . . . yes
C(1) N(1) C(2) 108.2(6) . . . yes
C(1) N(1) C(3) 108.9(6) . . . yes
C(2) N(1) C(3) 110.6(6) . . . yes
Os(1) N(2) C(4) 104.1(4) . . . yes
Os(1) N(2) C(5) 112.4(5) . . . yes
Os(1) N(2) C(6) 112.2(5) . . . yes
C(4) N(2) C(5) 111.5(6) . . . yes
C(4) N(2) C(6) 108.6(6) . . . yes
C(5) N(2) C(6) 108.0(6) . . . yes
C(9) N(3) C(13) 122.7(6) . . . yes
C(9) N(3) H(3n) 120(3) . . . no
C(13) N(3) H(3n) 115(3) . . . no
N(1) C(1) H(1a) 108.8 . . . no
N(1) C(1) H(1b) 109.8 . . . no
N(1) C(1) H(1c) 110.3 . . . no
H(1a) C(1) H(1b) 108.2 . . . no
H(1a) C(1) H(1c) 109.2 . . . no
H(1b) C(1) H(1c) 110.5 . . . no
N(1) C(2) H(2a) 109.1 . . . no
N(1) C(2) H(2b) 110.5 . . . no
N(1) C(2) H(2c) 110.3 . . . no
H(2a) C(2) H(2b) 108.6 . . . no
H(2a) C(2) H(2c) 108.1 . . . no
H(2b) C(2) H(2c) 110.2 . . . no
N(1) C(3) C(4) 111.7(6) . . . yes
N(1) C(3) H(3a) 108.8 . . . no
N(1) C(3) H(3b) 108.7 . . . no
C(4) C(3) H(3a) 108.5 . . . no
C(4) C(3) H(3b) 109.7 . . . no
H(3a) C(3) H(3b) 109.5 . . . no
N(2) C(4) C(3) 111.5(6) . . . yes
N(2) C(4) H(4a) 107.6 . . . no
N(2) C(4) H(4b) 107.6 . . . no
C(3) C(4) H(4a) 109.6 . . . no
C(3) C(4) H(4b) 110.3 . . . no
H(4a) C(4) H(4b) 110.2 . . . no
N(2) C(5) H(5c) 110.9 . . . no
N(2) C(5) H(5a) 111.0 . . . no
N(2) C(5) H(5b) 109.2 . . . no
H(5c) C(5) H(5a) 111.0 . . . no
H(5c) C(5) H(5b) 106.9 . . . no
H(5a) C(5) H(5b) 107.7 . . . no
N(2) C(6) H(6c) 110.8 . . . no
N(2) C(6) H(6a) 109.2 . . . no
N(2) C(6) H(6b) 111.5 . . . no
H(6c) C(6) H(6a) 106.2 . . . no
H(6c) C(6) H(6b) 110.9 . . . no
H(6a) C(6) H(6b) 108.0 . . . no
O(3) C(7) C(8) 106.5(5) . . . yes
O(3) C(7) C(12) 111.5(5) . . . yes
O(3) C(7) H(7) 110.1 . . . no
C(8) C(7) C(12) 114.2(6) . . . yes
C(8) C(7) H(7) 107.0 . . . no
C(12) C(7) H(7) 107.5 . . . no
O(4) C(8) C(7) 108.8(5) . . . yes
O(4) C(8) C(9) 108.1(5) . . . yes
O(4) C(8) H(8) 109.3 . . . no
C(7) C(8) C(9) 113.3(5) . . . yes
C(7) C(8) H(8) 109.8 . . . no
C(9) C(8) H(8) 107.5 . . . no
N(3) C(9) C(8) 106.6(5) . . . yes
N(3) C(9) C(10) 112.2(6) . . . yes
N(3) C(9) H(9) 108.4 . . . no
C(8) C(9) C(10) 112.0(5) . . . yes
C(8) C(9) H(9) 109.2 . . . no
C(10) C(9) H(9) 108.3 . . . no
C(9) C(10) C(11) 109.7(6) . . . yes
C(9) C(10) H(10b) 109.3 . . . no
C(9) C(10) H(10a) 109.6 . . . no
C(11) C(10) H(10b) 109.2 . . . no
C(11) C(10) H(10a) 109.8 . . . no
H(10b) C(10) H(10a) 109.2 . . . no
C(10) C(11) C(12) 107.6(5) . . . yes
C(10) C(11) C(15) 113.1(6) . . . yes
C(10) C(11) H(11) 106.9 . . . no
C(12) C(11) C(15) 114.2(5) . . . yes
C(12) C(11) H(11) 108.0 . . . no
C(15) C(11) H(11) 106.7 . . . no
C(7) C(12) C(11) 112.4(5) . . . yes
C(7) C(12) H(12a) 109.4 . . . no
C(7) C(12) H(12b) 109.2 . . . no
C(11) C(12) H(12a) 107.6 . . . no
C(11) C(12) H(12b) 107.9 . . . no
H(12a) C(12) H(12b) 110.3 . . . no
O(5) C(13) N(3) 125.6(7) . . . yes
O(5) C(13) C(14) 118.3(6) . . . yes
N(3) C(13) C(14) 116.0(6) . . . yes
Cl(1) C(14) Cl(2) 108.4(4) . . . yes
Cl(1) C(14) Cl(3) 108.5(4) . . . yes
Cl(1) C(14) C(13) 114.0(5) . . . yes
Cl(2) C(14) Cl(3) 110.0(4) . . . yes
Cl(2) C(14) C(13) 109.8(5) . . . yes
Cl(3) C(14) C(13) 106.0(5) . . . yes
C(11) C(15) C(16) 110.6(6) . . . yes
C(11) C(15) C(17) 111.6(6) . . . yes
C(11) C(15) C(18) 109.8(6) . . . yes
C(16) C(15) C(17) 108.4(6) . . . yes
C(16) C(15) C(18) 108.0(6) . . . yes
C(17) C(15) C(18) 108.3(6) . . . yes
C(15) C(16) H(16b) 108.6 . . . no
C(15) C(16) H(16c) 109.4 . . . no
C(15) C(16) H(16a) 109.0 . . . no
H(16b) C(16) H(16c) 109.8 . . . no
H(16b) C(16) H(16a) 109.7 . . . no
H(16c) C(16) H(16a) 110.4 . . . no
C(15) C(17) H(17b) 108.8 . . . no
C(15) C(17) H(17c) 110.1 . . . no
C(15) C(17) H(17a) 109.4 . . . no
H(17b) C(17) H(17c) 109.5 . . . no
H(17b) C(17) H(17a) 108.3 . . . no
H(17c) C(17) H(17a) 110.7 . . . no
C(15) C(18) H(18b) 108.3 . . . no
C(15) C(18) H(18c) 107.9 . . . no
C(15) C(18) H(18a) 109.4 . . . no
H(18b) C(18) H(18c) 109.0 . . . no
H(18b) C(18) H(18a) 111.3 . . . no
H(18c) C(18) H(18a) 110.8 . . . no
Cl(4) C(19) Cl(5) 113.8(6) . . . yes
Cl(4) C(19) H(19b) 109.1 . . . no
Cl(4) C(19) H(19a) 109.3 . . . no
Cl(5) C(19) H(19b) 107.3 . . . no
Cl(5) C(19) H(19a) 107.6 . . . no
H(19b) C(19) H(19a) 109.8 . . . no
#------------------------------------------------------------------------------
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_site_symmetry_1
_geom_contact_site_symmetry_2
_geom_contact_publ_flag
Cl(1) C(17) 3.584(9) . 2_566 no
Cl(2) O(2) 2.944(5) . 2_565 no
Cl(3) O(1) 3.212(5) . 2_566 no
Cl(5) C(16) 3.546(8) . 1_545 no
O(2) C(19) 3.45(1) . 2_656 no
O(3) C(19) 3.34(1) . 2_656 no
O(3) C(1) 3.522(9) . 2_656 no
O(5) C(2) 3.486(9) . 1_565 no
#------------------------------------------------------------------------------
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Os(1) O(3) C(7) C(8) . . . . -36.0(6) no
Os(1) O(3) C(7) C(12) . . . . 89.1(5) no
Os(1) O(4) C(8) C(7) . . . . -37.4(6) no
Os(1) O(4) C(8) C(9) . . . . -160.8(4) no
Os(1) N(1) C(3) C(4) . . . . 42.2(7) no
Os(1) N(2) C(4) C(3) . . . . 41.1(7) no
Cl(1) C(14) C(13) O(5) . . . . 165.0(6) no
Cl(1) C(14) C(13) N(3) . . . . -17.3(8) no
Cl(2) C(14) C(13) O(5) . . . . 43.1(9) no
Cl(2) C(14) C(13) N(3) . . . . -139.2(5) no
Cl(3) C(14) C(13) O(5) . . . . -75.7(8) no
Cl(3) C(14) C(13) N(3) . . . . 102.0(6) no
O(1) Os(1) O(3) C(7) . . . . -83.0(4) no
O(1) Os(1) O(4) C(8) . . . . 110.4(4) no
O(1) Os(1) N(1) C(1) . . . . -47.7(5) no
O(1) Os(1) N(1) C(2) . . . . -169.8(5) no
O(1) Os(1) N(1) C(3) . . . . 69.5(5) no
O(1) Os(1) N(2) C(4) . . . . -97.0(5) no
O(1) Os(1) N(2) C(5) . . . . 23.8(5) no
O(1) Os(1) N(2) C(6) . . . . 145.7(5) no
O(2) Os(1) O(3) C(7) . . . . 108.4(4) no
O(2) Os(1) O(4) C(8) . . . . -82.8(4) no
O(2) Os(1) N(1) C(1) . . . . 145.2(5) no
O(2) Os(1) N(1) C(2) . . . . 23.1(5) no
O(2) Os(1) N(1) C(3) . . . . -97.6(5) no
O(2) Os(1) N(2) C(4) . . . . 71.9(5) no
O(2) Os(1) N(2) C(5) . . . . -167.3(5) no
O(2) Os(1) N(2) C(6) . . . . -45.4(5) no
O(3) Os(1) O(4) C(8) . . . . 14.1(4) no
O(3) Os(1) N(1) C(1) . . . . 48.4(5) no
O(3) Os(1) N(1) C(2) . . . . -73.7(5) no
O(3) Os(1) N(1) C(3) . . . . 165.6(5) no
O(3) Os(1) N(2) C(4) . . . . -11(14) no
O(3) Os(1) N(2) C(5) . . . . 109(13) no
O(3) Os(1) N(2) C(6) . . . . -128(13) no
O(3) C(7) C(8) O(4) . . . . 47.9(6) no
O(3) C(7) C(8) C(9) . . . . 168.1(5) no
O(3) C(7) C(12) C(11) . . . . -171.7(5) no
O(4) Os(1) O(3) C(7) . . . . 13.3(4) no
O(4) Os(1) N(1) C(1) . . . . -117(10) no
O(4) Os(1) N(1) C(2) . . . . 120(10) no
O(4) Os(1) N(1) C(3) . . . . 0(10) no
O(4) Os(1) N(2) C(4) . . . . 166.8(5) no
O(4) Os(1) N(2) C(5) . . . . -72.4(5) no
O(4) Os(1) N(2) C(6) . . . . 49.5(5) no
O(4) C(8) C(7) C(12) . . . . -75.6(7) no
O(4) C(8) C(9) N(3) . . . . -50.6(7) no
O(4) C(8) C(9) C(10) . . . . 72.5(7) no
O(5) C(13) N(3) C(9) . . . . -1(1) no
N(1) Os(1) O(3) C(7) . . . . -166.4(4) no
N(1) Os(1) O(4) C(8) . . . . 179(10) no
N(1) Os(1) N(2) C(4) . . . . -13.5(5) no
N(1) Os(1) N(2) C(5) . . . . 107.3(5) no
N(1) Os(1) N(2) C(6) . . . . -130.8(5) no
N(1) C(3) C(4) N(2) . . . . -59.7(9) no
N(2) Os(1) O(3) C(7) . . . . -168(13) no
N(2) Os(1) O(4) C(8) . . . . -165.8(4) no
N(2) Os(1) N(1) C(1) . . . . -131.7(5) no
N(2) Os(1) N(1) C(2) . . . . 106.3(5) no
N(2) Os(1) N(1) C(3) . . . . -14.5(5) no
N(3) C(9) C(8) C(7) . . . . -171.2(5) no
N(3) C(9) C(10) C(11) . . . . 177.7(5) no
C(1) N(1) C(3) C(4) . . . . 160.7(6) no
C(2) N(1) C(3) C(4) . . . . -80.5(8) no
C(3) C(4) N(2) C(5) . . . . -80.3(8) no
C(3) C(4) N(2) C(6) . . . . 160.8(7) no
C(7) C(8) C(9) C(10) . . . . -48.2(8) no
C(7) C(12) C(11) C(10) . . . . 59.1(7) no
C(7) C(12) C(11) C(15) . . . . -174.5(6) no
C(8) C(7) C(12) C(11) . . . . -51.0(8) no
C(8) C(9) N(3) C(13) . . . . -158.9(6) no
C(8) C(9) C(10) C(11) . . . . 57.9(7) no
C(9) N(3) C(13) C(14) . . . . -178.8(6) no
C(9) C(8) C(7) C(12) . . . . 44.6(8) no
C(9) C(10) C(11) C(12) . . . . -62.3(7) no
C(9) C(10) C(11) C(15) . . . . 170.7(5) no
C(10) C(9) N(3) C(13) . . . . 78.1(8) no
C(10) C(11) C(15) C(16) . . . . -61.4(7) no
C(10) C(11) C(15) C(17) . . . . 59.4(8) no
C(10) C(11) C(15) C(18) . . . . 179.5(6) no
C(12) C(11) C(15) C(16) . . . . 175.1(6) no
C(12) C(11) C(15) C(17) . . . . -64.1(8) no
C(12) C(11) C(15) C(18) . . . . 56.0(8) no
#------------------------------------------------------------------------------
loop_
_geom_bond_atom_site_label_d
_geom_bond_atom_site_label_h
_geom_contact_atom_site_label_a
_geom_bond_distance_dh
_geom_contact_distance_ha
_geom_contact_distance_da
_geom_angle_dha
_geom_contact_site_symmetry_a
N(3) H(3n) O(4) 0.93 2.30 2.667(7) 102.7 .
N(3) H(3n) Cl(1) 0.93 2.41 2.923(6) 114.7 .

data_s893
_database_code_CSD               207039
#------------------------------------------------------------------------------
_audit_creation_date             19100-10-03
_audit_creation_method           'by teXsan v1.7'
_audit_update_record             
;
?
;

_publ_section_exptl_refinement   
;
The data were collected using the RAXIS in 90 x 3 degree 
phi oscillations, of 5 minutes per exposure.  The structure was
solved by direct methods. The non-H atoms,
were refined anisotropically, whilst H atoms
were included in calculated positions. 
Possible H bonding interactions are as follows:

Hydrogen bonds with  H..A < r(A) + 2.000 Angstroms  and  <DHA > 110 deg.

D-H           d(D-H)   d(H..A)   <DHA    d(D..A)   A

N1-H1          0.860    2.182   161.59    3.010    O4 
N1-H1          0.860    2.575   111.56    2.999    Cl1 

;

_publ_section_comment            
;
ENTER TEXT
;

_publ_section_references         
;
ENTER OTHER REFERENCES

Molecular Structure Corporation. (1995). teXsan. 
Single Crystal Structure Analysis Software. Version 1.7.
MSC, 3200 Research Forest Drive, The Woodlands, TX 77381, USA.

Altomare, A., Cascarano, M., 
Giacovazzo, C., Guagliardi, A. (1993). 
J. Appl. Cryst., 26, 343. 
;

_chemical_name_common            ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C13 H24 Cl3 N3 O5 Os'
_chemical_formula_weight         598.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c     '
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  ?

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.19(2)
_cell_length_b                   11.405(10)
_cell_length_c                   15.857(10)
_cell_angle_alpha                90.00
_cell_angle_beta                 102.57(4)
_cell_angle_gamma                90.00
_cell_volume                     1976(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    49058
_cell_measurement_theta_min      1.86
_cell_measurement_theta_max      26.36

_exptl_crystal_description       block
_exptl_crystal_colour            brown
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.1
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.013
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1160
_exptl_absorpt_coefficient_mu    6.888
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?

_exptl_special_details           
; 
? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_detector       'scintillation counter'
_diffrn_measurement_device       'Rigaku RAXIS'
_diffrn_measurement_method       '90 x 3 degree phi scans'

_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_decay_%        0.00
_diffrn_reflns_number            49058
_diffrn_reflns_av_R_equivalents  0.054
_diffrn_reflns_av_sigmaI/netI    0.0275
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.86
_diffrn_reflns_theta_max         26.36
_reflns_number_total             3844
_reflns_number_gt                3605
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'DENZO (Otwinowski, Z. 1988)'
_computing_structure_solution    
;
SIR92 (Altomare, et. al. 1993)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_publication_material  'teXsan (MSC, 1995)'

_refine_special_details          
; 
Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
goodness of fit S are based on F^2^, conventional R-factors R are based 
on F, with F set to zero for negative F^2^. The threshold expression of 
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
not relevant to the choice of reflections for refinement.  R-factors based 
on F^2^ are statistically about twice as large as those based on F, and R- 
factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      
'calc w=1/[\s^2^(Fo^2^)+(0.0364P)^2^+2.5867P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3844
_refine_ls_number_parameters     230
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0261
_refine_ls_R_factor_gt           0.0240
_refine_ls_wR_factor_ref         0.0629
_refine_ls_wR_factor_gt          0.0619
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_restrained_S_all      1.023
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.725220(11) -0.178723(11) 0.310098(8) 0.02275(7) Uani 1 d . . .
Cl1 Cl 1.07904(9) -0.37751(8) 0.47309(6) 0.0390(2) Uani 1 d . . .
Cl2 Cl 1.33754(11) -0.33901(12) 0.51567(9) 0.0612(3) Uani 1 d . . .
Cl3 Cl 1.17519(13) -0.16351(10) 0.56033(8) 0.0522(3) Uani 1 d . . .
O1 O 0.8406(2) -0.0485(2) 0.33207(16) 0.0333(6) Uani 1 d . . .
O2 O 0.7532(3) -0.1737(2) 0.19321(18) 0.0381(7) Uani 1 d . . .
O3 O 1.2859(3) -0.1632(4) 0.3835(3) 0.0781(14) Uani 1 d . . .
O4 O 0.8350(2) -0.2852(2) 0.34952(17) 0.0304(5) Uani 1 d . . .
O5 O 0.5913(3) -0.0982(2) 0.28961(18) 0.0395(6) Uani 1 d . . .
N1 N 1.0819(3) -0.1836(3) 0.3458(2) 0.0344(8) Uani 1 d . . .
H1 H 1.0187 -0.2146 0.3593 0.041 Uiso 1 calc R . .
N2 N 0.6902(3) -0.1928(3) 0.4437(2) 0.0291(7) Uani 1 d . . .
N3 N 0.5979(3) -0.3312(2) 0.2878(2) 0.0300(7) Uani 1 d . . .
C1 C 0.8772(4) -0.0052(3) 0.2564(2) 0.0327(8) Uani 1 d . . .
H1' H 0.8356 0.0686 0.2366 0.039 Uiso 1 calc R . .
C2 C 1.0158(4) 0.0103(3) 0.2772(2) 0.0356(9) Uani 1 d . . .
H2A H 1.0444 0.0388 0.3358 0.043 Uiso 1 calc R . .
H2B H 1.0406 0.0651 0.2375 0.043 Uiso 1 calc R . .
C3 C 1.0667(3) -0.1126(3) 0.2669(2) 0.0330(8) Uani 1 d . . .
H3 H 1.1457 -0.1055 0.2502 0.040 Uiso 1 calc R . .
C4 C 0.9729(4) -0.1653(3) 0.1922(3) 0.0386(9) Uani 1 d . . .
H4A H 0.9611 -0.2478 0.2028 0.046 Uiso 1 calc R . .
H4B H 1.0013 -0.1582 0.1388 0.046 Uiso 1 calc R . .
C5 C 0.8521(3) -0.0985(3) 0.1849(2) 0.0317(8) Uani 1 d . . .
H5 H 0.8315 -0.0593 0.1287 0.038 Uiso 1 calc R . .
C6 C 1.1908(4) -0.2005(3) 0.3962(3) 0.0342(8) Uani 1 d . . .
C7 C 1.1942(3) -0.2692(3) 0.4822(2) 0.0330(8) Uani 1 d . . .
C8 C 0.6433(4) -0.3142(3) 0.4476(3) 0.0418(10) Uani 1 d . . .
H8A H 0.6079 -0.3223 0.4980 0.050 Uiso 1 calc R . .
H8B H 0.7105 -0.3694 0.4532 0.050 Uiso 1 calc R . .
C9 C 0.5469(4) -0.3421(4) 0.3665(3) 0.0415(10) Uani 1 d . . .
H9A H 0.5169 -0.4213 0.3704 0.050 Uiso 1 calc R . .
H9B H 0.4783 -0.2887 0.3622 0.050 Uiso 1 calc R . .
C10 C 0.8068(4) -0.1787(4) 0.5097(3) 0.0454(11) Uani 1 d . . .
H10A H 0.7921 -0.1942 0.5661 0.068 Uiso 1 calc R . .
H10B H 0.8365 -0.1001 0.5077 0.068 Uiso 1 calc R . .
H10C H 0.8666 -0.2329 0.4978 0.068 Uiso 1 calc R . .
C11 C 0.6011(4) -0.1056(4) 0.4630(3) 0.0496(11) Uani 1 d . . .
H11A H 0.5240 -0.1154 0.4229 0.074 Uiso 1 calc R . .
H11B H 0.6315 -0.0279 0.4576 0.074 Uiso 1 calc R . .
H11C H 0.5903 -0.1173 0.5208 0.074 Uiso 1 calc R . .
C12 C 0.6611(4) -0.4412(3) 0.2715(3) 0.0466(11) Uani 1 d . . .
H12A H 0.7192 -0.4634 0.3230 0.070 Uiso 1 calc R . .
H12B H 0.7030 -0.4285 0.2255 0.070 Uiso 1 calc R . .
H12C H 0.6018 -0.5026 0.2555 0.070 Uiso 1 calc R . .
C13 C 0.4959(4) -0.3126(4) 0.2115(3) 0.0492(12) Uani 1 d . . .
H13A H 0.4422 -0.3792 0.2043 0.074 Uiso 1 calc R . .
H13B H 0.5286 -0.3031 0.1607 0.074 Uiso 1 calc R . .
H13C H 0.4511 -0.2435 0.2201 0.074 Uiso 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Os1 0.02093(10) 0.02327(10) 0.02462(10) 0.00032(5) 0.00618(6) -0.00044(4)
Cl1 0.0385(5) 0.0372(5) 0.0424(5) 0.0013(4) 0.0114(4) -0.0054(4)
Cl2 0.0336(6) 0.0802(9) 0.0683(8) 0.0199(6) 0.0081(6) 0.0157(5)
Cl3 0.0649(8) 0.0509(6) 0.0445(6) -0.0164(5) 0.0201(5) -0.0112(5)
O1 0.0419(15) 0.0297(13) 0.0309(13) -0.0071(11) 0.0138(11) -0.0100(12)
O2 0.0438(17) 0.0418(18) 0.0303(16) -0.0063(10) 0.0114(13) -0.0178(12)
O3 0.0308(18) 0.124(4) 0.078(3) 0.047(2) 0.0069(18) -0.0166(19)
O4 0.0196(12) 0.0307(13) 0.0418(14) -0.0017(12) 0.0089(10) 0.0012(10)
O5 0.0374(15) 0.0360(14) 0.0432(15) 0.0057(12) 0.0048(12) 0.0089(12)
N1 0.0259(16) 0.0426(19) 0.0373(18) 0.0109(13) 0.0126(14) -0.0030(13)
N2 0.0242(16) 0.0381(17) 0.0269(16) 0.0036(12) 0.0095(13) 0.0013(12)
N3 0.0208(15) 0.0285(16) 0.0397(18) -0.0034(13) 0.0043(13) -0.0036(11)
C1 0.043(2) 0.0234(16) 0.0332(18) 0.0041(15) 0.0117(16) -0.0042(16)
C2 0.046(2) 0.0282(18) 0.0347(19) -0.0011(15) 0.0124(17) -0.0165(17)
C3 0.0326(19) 0.0359(19) 0.0335(19) 0.0018(16) 0.0139(15) -0.0086(16)
C4 0.046(2) 0.038(2) 0.033(2) -0.0043(16) 0.0117(18) -0.0055(17)
C5 0.040(2) 0.0313(18) 0.0243(17) 0.0040(15) 0.0073(15) -0.0080(16)
C6 0.0263(19) 0.0395(19) 0.039(2) -0.0001(17) 0.0123(16) -0.0019(16)
C7 0.0263(18) 0.040(2) 0.0332(19) -0.0036(17) 0.0079(15) -0.0004(16)
C8 0.044(2) 0.045(2) 0.039(2) 0.0122(17) 0.0163(19) -0.0057(18)
C9 0.030(2) 0.043(2) 0.055(3) 0.0041(19) 0.0167(19) -0.0092(17)
C10 0.041(2) 0.067(3) 0.025(2) 0.0008(17) 0.0006(18) -0.0055(19)
C11 0.048(3) 0.057(3) 0.051(3) -0.007(2) 0.027(2) 0.010(2)
C12 0.029(2) 0.031(2) 0.078(3) -0.012(2) 0.009(2) -0.0061(17)
C13 0.032(2) 0.056(3) 0.051(3) -0.004(2) -0.010(2) -0.0095(18)

_geom_special_details            
; 
All esds (except the esd in the dihedral angle between two l.s. planes) 
are estimated using the full covariance matrix.  The cell esds are taken 
into account individually in the estimation of esds in distances, angles 
and torsion angles; correlations between esds in cell parameters are only 
used when they are defined by crystal symmetry.  An approximate (isotropic) 
treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Os1 O5 1.727(3) . ?
Os1 O4 1.744(3) . ?
Os1 O2 1.947(3) . ?
Os1 O1 1.949(2) . ?
Os1 N3 2.227(3) . ?
Os1 N2 2.243(3) . ?
Cl1 C7 1.768(4) . ?
Cl2 C7 1.767(4) . ?
Cl3 C7 1.774(4) . ?
O1 C1 1.438(4) . ?
O2 C5 1.429(4) . ?
O3 C6 1.204(5) . ?
N1 C6 1.318(5) . ?
N1 C3 1.469(5) . ?
N1 H1 0.8600 . ?
N2 C11 1.486(5) . ?
N2 C8 1.487(5) . ?
N2 C10 1.492(5) . ?
N3 C9 1.486(5) . ?
N3 C12 1.490(5) . ?
N3 C13 1.488(5) . ?
C1 C2 1.524(5) . ?
C1 C5 1.536(5) . ?
C1 H1 0.9800 . ?
C2 C3 1.534(5) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.526(5) . ?
C3 H3 0.9800 . ?
C4 C5 1.534(6) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 H5 0.9800 . ?
C6 C7 1.565(5) . ?
C8 C9 1.522(6) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Os1 O4 162.27(13) . . ?
O5 Os1 O2 96.77(13) . . ?
O4 Os1 O2 96.61(13) . . ?
O5 Os1 O1 98.19(12) . . ?
O4 Os1 O1 94.54(12) . . ?
O2 Os1 O1 84.86(10) . . ?
O5 Os1 N3 83.48(12) . . ?
O4 Os1 N3 83.64(12) . . ?
O2 Os1 N3 95.84(12) . . ?
O1 Os1 N3 178.11(11) . . ?
O5 Os1 N2 83.86(12) . . ?
O4 Os1 N2 82.28(12) . . ?
O2 Os1 N2 177.45(11) . . ?
O1 Os1 N2 97.51(11) . . ?
N3 Os1 N2 81.76(12) . . ?
C1 O1 Os1 114.3(2) . . ?
C5 O2 Os1 113.2(2) . . ?
C6 N1 C3 121.2(3) . . ?
C6 N1 H1 119.4 . . ?
C3 N1 H1 119.4 . . ?
C11 N2 C8 110.8(3) . . ?
C11 N2 C10 107.9(3) . . ?
C8 N2 C10 109.5(3) . . ?
C11 N2 Os1 114.2(2) . . ?
C8 N2 Os1 104.0(2) . . ?
C10 N2 Os1 110.4(3) . . ?
C9 N3 C12 111.1(3) . . ?
C9 N3 C13 109.1(3) . . ?
C12 N3 C13 106.7(3) . . ?
C9 N3 Os1 106.4(2) . . ?
C12 N3 Os1 112.0(2) . . ?
C13 N3 Os1 111.6(2) . . ?
O1 C1 C2 108.7(3) . . ?
O1 C1 C5 109.7(3) . . ?
C2 C1 C5 104.7(3) . . ?
O1 C1 H1 111.2 . . ?
C2 C1 H1 111.2 . . ?
C5 C1 H1 111.2 . . ?
C1 C2 C3 104.8(3) . . ?
C1 C2 H2A 110.8 . . ?
C3 C2 H2A 110.8 . . ?
C1 C2 H2B 110.8 . . ?
C3 C2 H2B 110.8 . . ?
H2A C2 H2B 108.9 . . ?
N1 C3 C4 112.1(3) . . ?
N1 C3 C2 112.9(3) . . ?
C4 C3 C2 103.5(3) . . ?
N1 C3 H3 109.4 . . ?
C4 C3 H3 109.4 . . ?
C2 C3 H3 109.4 . . ?
C3 C4 C5 108.0(3) . . ?
C3 C4 H4A 110.1 . . ?
C5 C4 H4A 110.1 . . ?
C3 C4 H4B 110.1 . . ?
C5 C4 H4B 110.1 . . ?
H4A C4 H4B 108.4 . . ?
O2 C5 C4 112.5(3) . . ?
O2 C5 C1 111.7(3) . . ?
C4 C5 C1 105.8(3) . . ?
O2 C5 H5 108.9 . . ?
C4 C5 H5 108.9 . . ?
C1 C5 H5 108.9 . . ?
O3 C6 N1 125.5(4) . . ?
O3 C6 C7 117.9(4) . . ?
N1 C6 C7 116.5(3) . . ?
C6 C7 Cl2 109.6(3) . . ?
C6 C7 Cl1 113.6(3) . . ?
Cl2 C7 Cl1 107.9(2) . . ?
C6 C7 Cl3 106.5(3) . . ?
Cl2 C7 Cl3 109.6(2) . . ?
Cl1 C7 Cl3 109.6(2) . . ?
N2 C8 C9 110.6(3) . . ?
N2 C8 H8A 109.5 . . ?
C9 C8 H8A 109.5 . . ?
N2 C8 H8B 109.5 . . ?
C9 C8 H8B 109.5 . . ?
H8A C8 H8B 108.1 . . ?
N3 C9 C8 111.1(3) . . ?
N3 C9 H9A 109.4 . . ?
C8 C9 H9A 109.4 . . ?
N3 C9 H9B 109.4 . . ?
C8 C9 H9B 109.4 . . ?
H9A C9 H9B 108.0 . . ?
N2 C10 H10A 109.5 . . ?
N2 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
N2 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
N2 C11 H11A 109.5 . . ?
N2 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
N2 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N3 C12 H12A 109.5 . . ?
N3 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
N3 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N3 C13 H13A 109.5 . . ?
N3 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
N3 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O5 Os1 O1 C1 -89.7(3) . . . . ?
O4 Os1 O1 C1 102.7(2) . . . . ?
O2 Os1 O1 C1 6.4(2) . . . . ?
N3 Os1 O1 C1 118(3) . . . . ?
N2 Os1 O1 C1 -174.5(2) . . . . ?
O5 Os1 O2 C5 107.6(3) . . . . ?
O4 Os1 O2 C5 -84.1(3) . . . . ?
O1 Os1 O2 C5 9.9(3) . . . . ?
N3 Os1 O2 C5 -168.3(3) . . . . ?
N2 Os1 O2 C5 -148(2) . . . . ?
O5 Os1 N2 C11 -17.1(3) . . . . ?
O4 Os1 N2 C11 173.9(3) . . . . ?
O2 Os1 N2 C11 -122(3) . . . . ?
O1 Os1 N2 C11 80.3(3) . . . . ?
N3 Os1 N2 C11 -101.4(3) . . . . ?
O5 Os1 N2 C8 103.7(3) . . . . ?
O4 Os1 N2 C8 -65.2(3) . . . . ?
O2 Os1 N2 C8 -1(3) . . . . ?
O1 Os1 N2 C8 -158.8(3) . . . . ?
N3 Os1 N2 C8 19.4(3) . . . . ?
O5 Os1 N2 C10 -138.9(3) . . . . ?
O4 Os1 N2 C10 52.2(2) . . . . ?
O2 Os1 N2 C10 117(3) . . . . ?
O1 Os1 N2 C10 -41.4(3) . . . . ?
N3 Os1 N2 C10 136.8(3) . . . . ?
O5 Os1 N3 C9 -75.3(2) . . . . ?
O4 Os1 N3 C9 92.5(2) . . . . ?
O2 Os1 N3 C9 -171.4(2) . . . . ?
O1 Os1 N3 C9 77(3) . . . . ?
N2 Os1 N3 C9 9.4(2) . . . . ?
O5 Os1 N3 C12 163.3(3) . . . . ?
O4 Os1 N3 C12 -29.0(3) . . . . ?
O2 Os1 N3 C12 67.1(3) . . . . ?
O1 Os1 N3 C12 -44(3) . . . . ?
N2 Os1 N3 C12 -112.0(3) . . . . ?
O5 Os1 N3 C13 43.7(3) . . . . ?
O4 Os1 N3 C13 -148.6(3) . . . . ?
O2 Os1 N3 C13 -52.5(3) . . . . ?
O1 Os1 N3 C13 -164(3) . . . . ?
N2 Os1 N3 C13 128.4(3) . . . . ?
Os1 O1 C1 C2 -133.9(2) . . . . ?
Os1 O1 C1 C5 -19.9(4) . . . . ?
O1 C1 C2 C3 82.0(3) . . . . ?
C5 C1 C2 C3 -35.2(4) . . . . ?
C6 N1 C3 C4 140.0(4) . . . . ?
C6 N1 C3 C2 -103.5(4) . . . . ?
C1 C2 C3 N1 -86.5(4) . . . . ?
C1 C2 C3 C4 35.0(4) . . . . ?
N1 C3 C4 C5 100.3(4) . . . . ?
C2 C3 C4 C5 -21.7(4) . . . . ?
Os1 O2 C5 C4 95.8(3) . . . . ?
Os1 O2 C5 C1 -23.1(4) . . . . ?
C3 C4 C5 O2 -121.8(3) . . . . ?
C3 C4 C5 C1 0.4(4) . . . . ?
O1 C1 C5 O2 27.6(4) . . . . ?
C2 C1 C5 O2 144.1(3) . . . . ?
O1 C1 C5 C4 -95.2(3) . . . . ?
C2 C1 C5 C4 21.3(4) . . . . ?
C3 N1 C6 O3 -1.2(7) . . . . ?
C3 N1 C6 C7 175.2(3) . . . . ?
O3 C6 C7 Cl2 -29.2(5) . . . . ?
N1 C6 C7 Cl2 154.1(3) . . . . ?
O3 C6 C7 Cl1 -150.0(4) . . . . ?
N1 C6 C7 Cl1 33.3(4) . . . . ?
O3 C6 C7 Cl3 89.2(5) . . . . ?
N1 C6 C7 Cl3 -87.5(4) . . . . ?
C11 N2 C8 C9 77.1(4) . . . . ?
C10 N2 C8 C9 -164.0(4) . . . . ?
Os1 N2 C8 C9 -46.0(4) . . . . ?
C12 N3 C9 C8 84.6(4) . . . . ?
C13 N3 C9 C8 -158.0(3) . . . . ?
Os1 N3 C9 C8 -37.5(4) . . . . ?
N2 C8 C9 N3 59.5(5) . . . . ?

_diffrn_measured_fraction_theta_max 0.906
_diffrn_reflns_theta_full        26.36
_diffrn_measured_fraction_theta_full 0.906
_refine_diff_density_max         0.920
_refine_diff_density_min         -1.444
_refine_diff_density_rms         0.115